rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Metal Dihydrogen and σ-Bond Complexes
    sub title: Structure Theory and Reactivity
  name:
    name part: Kubas, Gregory J.
    role:
      role term: creator
    role:
      role term: author.
  name:
    name part: SpringerLink (Online service)
  type of resource: text
  origin info:
    place:
      place term: xxu
    date issued: 2001
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: electronic
    form: electronic resource
    reformatting quality: access
    form: remote
    extent: XVI, 472 p. online resource.
  abstract: According to R.H. Crabtree, Metal Dihydrogen and sigma-Bond Complexes is described as `the definitive account of twentieth-century work in the area of sigma complexation'. It covers not only Kubas' discovery of dihydrogen coordination and the study of its structure and general properties but also discusses both the theoretical beliefs and experimental results of bonding and activation of dihydrogen on metal centers and the coordination and activation of C-H, B-H, X-H, and X-Y bonds, giving an overview of `one of the hottest areas in chemistry'.
  table of contents: Background and Discovery of Dihydrogen Coordination -- Synthesis and General Properties of Dihydrogen Complexes -- Bonding and Activation of Dihydrogen and ? Ligands: Theory versus Experiment -- Structural and NMR Studies of Dihydrogen Complexes -- Intramolecular Dynamics of Dihydrogen-hydride Ligand Systems: Hydrogen Rotation, Exchange, and Quantum-mechanical Effects -- Thermodynamics, Kinetics, and Isotope Effects of the Binding and Cleavage of ? Ligands versus Classical Ligands -- Vibrational Studies of Coordinated Dihydrogen -- Reactions and Acidity of Dihydrogen Complexes -- Activation of Hydrogen and Related Small Molecules by Metalloenzymes and Sulfur Ligand Systems -- Coordination and Activation of Si-H, Ge-H, and Sn-H Bonds -- C-H Bond Coordination and Activation -- Coordination and Activation of B-H and Other X-H and X-Y Bonds.
  note: by Gregory J. Kubas.
  subject:
    topic: Chemistry
  subject:
    topic: Inorganic chemistry
  subject:
    topic: Organometallic chemistry
  subject:
    topic: Physical chemistry
  subject:
    topic: Chemical engineering
  subject:
    topic: Chemistry
  subject:
    topic: Organometallic Chemistry
  subject:
    topic: Physical Chemistry
  subject:
    topic: Inorganic Chemistry
  subject:
    topic: Industrial Chemistry/Chemical Engineering
  classification: QD410-412.5
  classification: 547.05
  related item:
    title info:
      title: Springer eBooks
  related item:
    title info:
      title: Modern Inorganic Chemistry
  identifier: 9780306475979
  identifier: http://dx.doi.org/10.1007/b113929
  record info:
    record creation date: 100301
    record change date: 20151028141716.0
    record identifier: 978-0-306-47597-9