rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Organometallic Modeling of the Hydrodesulfurization and Hydrodenitrogenation Reactions
  name:
    name part: Sánchez-Delgado, Roberto A.
    role:
      role term: creator
    role:
      role term: author.
  name:
    name part: SpringerLink (Online service)
  type of resource: text
  origin info:
    place:
      place term: ne
    date issued: 2002
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: electronic
    form: electronic resource
    reformatting quality: access
    form: remote
    extent: XII, 212 p. 31 illus. online resource.
  abstract: The fields of hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) continue to attract the attention of researchers in the various disciplines connected to these fascinating problems that represent two of the key outstanding chemical challenges for the petroleum refining industry in view of their very strong environmental and commercial implications. One area that has flourished impressively over the last 15 years is the organometallic chemistry of thiophenes and other related sulfur-containing molecules. This has become a powerful method for modeling numerous surface species and reactions implicated in HDS schemes, and nowadays it represents an attractive complement to the standard procedures of surface chemistry and heterogeneous catalysis, for understanding the complex reaction mechanisms involved in this process. Similar developments have begun to appear in connection with HDN mechanisms, although in a much more modest scale and depth. Some years ago when, encouraged by Prof. B. R. James, this book was planned, several excellent reviews and monographs treating different aspects of HDS were already available including some on the subject of organometallic models. However, it seemed appropriate to try to summarize the most striking features of this chemistry in an updated and systematic way, and inasmuch as possible in connection with the common knowledge and beliefs of the mechanisms of heterogeneous HDS catalysis. Hopefully, this attempt to build some conceptual bridges between these two traditionally separated areas of chemistry has met with some success.
  table of contents: Hydrodesulfurization and Hydrodenitrogenation -- Coordination and Activation of Thiophenes in Metal Complexes -- Hydrogenation Reactions -- Ring Opening, Hydrogenolysis and Desulfurization of Thiophenes by Metal Complexes -- Activation of Hydrogen on Metal Complexes with Sulfide Ligands and Related Coordination Chemistry of H2S -- Modeling Hydrodenitrogenation.
  note: by Roberto A. Sánchez-Delgado.
  subject:
    topic: Chemistry
  subject:
    topic: Inorganic chemistry
  subject:
    topic: Organic chemistry
  subject:
    topic: Organometallic chemistry
  subject:
    topic: Physical chemistry
  subject:
    topic: Chemical engineering
  subject:
    topic: Catalysis
  subject:
    topic: Chemistry
  subject:
    topic: Organometallic Chemistry
  subject:
    topic: Catalysis
  subject:
    topic: Physical Chemistry
  subject:
    topic: Inorganic Chemistry
  subject:
    topic: Industrial Chemistry/Chemical Engineering
  subject:
    topic: Organic Chemistry
  classification: QD410-412.5
  classification: 547.05
  related item:
    title info:
      title: Springer eBooks
  related item:
    title info:
      title: Catalysis by Metal Complexes, 24
  identifier: 9780306476198
  identifier: http://dx.doi.org/10.1007/0-306-47619-3
  record info:
    record creation date: 100301
    record change date: 20151103122259.0
    record identifier: 978-0-306-47619-8