rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    non sort: The
    title: Inorganic Radiochemistry of Heavy Elements
    sub title: Methods for Studying Gaseous Compounds
  name:
    name part: Zvára, Ivo.
    role:
      role term: creator
    role:
      role term: author.
  name:
    name part: SpringerLink (Online service)
  type of resource: text
  origin info:
    place:
      place term: ne
    date issued: 2008
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: electronic
    form: electronic resource
    reformatting quality: access
    form: remote
    extent: XXVIII, 228 p. online resource.
  abstract: The aim of this book is to facilitate the wider use of advantageous gas phase techniques towards heavy elements. Studies of the transactinoid elements (polyvalent metals) stimulated application of their volatile halides, oxides, and oxyhalides to fast radiochemical separations. Selected results are presented here. Primarily, this book features the physico-chemical basis of experimental methods and techniques. It focuses on evaluation of the desorption energy from data of a single gas-solid chromatography experiment through calculation of desorption entropy. Heterogeneity of the column surface and its chemical modification are taken into account. Several approaches to the estimation of bulk properties of the compounds from experiments with only a few atoms are also discussed. The accuracy of the derived quantities is then analyzed using the Bayesian statistical approach. The book is aimed at newcomers to the field as well as experts actively engaged in this area of research.
  table of contents: Experimental developments in inorganic gas phase radiochemistry: Early gas–solid chromatography studies -- Techniques for isolation of short-lived accelerator produced activities -- Techniques for alpha-active nuclides with corrosive reagents -- Recent techniques for alpha-active nuclides in non corrosive environment -- Future of radiochemistry studies of heavy metals -- Physicochemical Fundamentals: Molecular kinetics -- Diffusional deposition of molecules and aerosols in channels -- Statistical thermodynamics of adsorption -- Production of transactinoid elements, synthesis and transportation of their compounds: Production of TAE in heavy ion induced reactions -- Synthesis of volatile compounds -- Scavenging of impurities in the gas -- Deposition of nonvolatile elements and compounds from gas flow -- Aerosol stream for transportation of molecular entities -- From gas-solid isothermal chromatography to thermochromatography: General considerations -- Theory -- Simulation of IC and TC peak shape and position -- Vacuum thermochromatography -- Evaluation and interpretation of experimental data: Evaluation of desorption energy / enthalpy from the experimental data -- Experimental adsorption enthalpies of heavy element compounds -- True structure of the column surfaces -- Analysis of poor-statistics data.
  note: by Ivo Zvára.
  subject:
    topic: Chemistry
  subject:
    topic: Analytical chemistry
  subject:
    topic: Inorganic chemistry
  subject:
    topic: Physical chemistry
  subject:
    topic: Nuclear chemistry
  subject:
    topic: Nuclear physics
  subject:
    topic: Heavy ions
  subject:
    topic: Hadrons
  subject:
    topic: Chemistry
  subject:
    topic: Analytical Chemistry
  subject:
    topic: Nuclear Chemistry
  subject:
    topic: Inorganic Chemistry
  subject:
    topic: Physical Chemistry
  subject:
    topic: Nuclear Physics, Heavy Ions, Hadrons
  classification: QD71-142
  classification: 543
  related item:
    title info:
      title: Springer eBooks
  identifier: 9781402066023
  identifier: http://dx.doi.org/10.1007/978-1-4020-6602-3
  record info:
    record creation date: 100301
    record change date: 20151204173608.0
    record identifier: 978-1-4020-6602-3