rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Bonding in Electron-Rich Molecules
    sub title: Qualitative Valence-Bond Approach via Increased-Valence Structures
  name:
    name part: Harcourt, Richard D.
    role:
      role term: creator
    role:
      role term: author.
  name:
    name part: SpringerLink (Online service)
  type of resource: text
  origin info:
    place:
      place term: gw
    date issued: 2016
    edition: 2nd ed. 2016.
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: electronic
    form: electronic resource
    reformatting quality: access
    form: remote
    extent: XV, 326 p. online resource.
  abstract: This second edition was updated to include some of the recent developments, such as “increased-valence” structures for 3-electron-3-centre bonding, benzene, electron conduction and reaction mechanisms, spiral chain O4 polymers and recoupled-pair bonding. The author provides qualitative molecular orbital and valence-bond descriptions of the electronic structures for primarily electron-rich molecules, with strong emphasis given to the valence-bond approach that uses “increased-valence” structures. He describes how “long-bond” Lewis structures as well as standard Lewis structures are incorporated into “increased-valence” structures for electron-rich molecules. “Increased-valence” structures involve more electrons in bonding than do their component Lewis structures, and are used to provide interpretations for molecular electronic structure, bond properties and reactivities. Attention is also given to Pauling “3-electron bonds”, which are usually diatomic components of “increased-valence” structures for electron-rich molecules.
  table of contents: From the Contents: Atomic Orbitals, Electron Spin, Linear Combinations -- Pauling ‘3-Electron Bonds’, 4-Electron 3-Centre Bonding, and the Need for an ‘Increased Valence’ Theory -- Wave-Functions and Valence-Bond Structures for 1-Electron Bonds, Electron-Pair Bonds, Pauling ‘3-Electron Bonds’ and ‘No Bonds’ -- Valence-Bond Structures for Some Diatomic Molecules.
  note: by Richard D. Harcourt.
  subject:
    topic: Chemistry
  subject:
    topic: Organic chemistry
  subject:
    topic: Chemistry, Physical and theoretical
  subject:
    topic: Atomic structure
  subject:
    topic: Molecular structure
  subject:
    topic: Spectra
  subject:
    topic: Chemistry
  subject:
    topic: Theoretical and Computational Chemistry
  subject:
    topic: Atomic/Molecular Structure and Spectra
  subject:
    topic: Organic Chemistry
  classification: QD450-801
  classification: 541.2
  related item:
    title info:
      title: Springer eBooks
  related item:
    title info:
      title: Lecture Notes in Chemistry, 90
  identifier: 9783319166766
  identifier: http://dx.doi.org/10.1007/978-3-319-16676-6
  record info:
    record creation date: 151030
    record change date: 20170520141358.0
    record identifier: 978-3-319-16676-6