rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Organometallic Oxidation Catalysis
  title info:
    title: With contributions by numerous experts
  name:
    name part: Meyer, Franc.
    role:
      role term: editor.
  name:
    name part: Limberg, Christian.
    role:
      role term: editor.
  name:
    name part: SpringerLink (Online service)
  type of resource: text
  origin info:
    place:
      place term: gw
    date issued: 2007
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: electronic
    form: electronic resource
    reformatting quality: access
    form: remote
    extent: XI, 253 p. online resource.
  abstract: Eighty per cent of all compounds produced in the chemical and pharmaceutical industries require at least one essential catalytic step during their synthesis. At the same time the use of hydrocarbons as a feed-stock for commodity and fine chemicals typically requires an oxidation step, which is usually mediated by a transition metal compound. Consequently oxidation catalysis is a major research field in chemistry, both in academia and in industry. In many such processes, species with metal-carbon bonds are formed as key intermediates, and these processes represent the primary focus of this volume. An important aspect covered by some of the expert contributors is the use of organic ligands - and thus organometallic complex metal fragments - to achieve efficient oxidation catalysis. It has not been self-evident that organometallic complexes can survive the conditions necessary for polar oxygen-transfer reactions, but research over the last decade concerning oxo and peroxo complexes functionalized by organic ligands has clearly shown that relatively non-polar M-C bonds can be quite stable in the presence of oxidants and protic media, and that they may even be essential for the favourable activity and life-time of a catalyst. Also considered in this context is the oxidation chemistry of basic organometallic species in the gas phase, as this may reveal fundamental characteristics inherent to oxidation catalysts.
  table of contents: Intrinsic Mechanisms of Oxidation Reactions as Revealed by Gas-Phase Experiments -- Dioxygen Activation by Organometallics of Early Transition Metals -- Organorhenium and Organomolybdenum Oxides as Heterogenised Catalysts -- The SOHIO Process as an Inspiration for Molecular Organometallic Chemistry -- Catalysis and Organometallic Chemistry of Rhodium and Iridium in the Oxidation of Organic Substrates -- The Role of NHC Ligands in Oxidation Catalysis -- Palladium-Catalyzed Oxidation Reactions: Comparison of Benzoquinone and Molecular Oxygen as Stoichiometric Oxidants -- Homogeneous Copper-Catalyzed Oxidations.
  note: edited by Franc Meyer, Christian Limberg.
  subject:
    topic: Chemistry
  subject:
    topic: Inorganic chemistry
  subject:
    topic: Organometallic chemistry
  subject:
    topic: Medicinal chemistry
  subject:
    topic: Catalysis
  subject:
    topic: Chemistry
  subject:
    topic: Organometallic Chemistry
  subject:
    topic: Catalysis
  subject:
    topic: Inorganic Chemistry
  subject:
    topic: Medicinal Chemistry
  classification: QD410-412.5
  classification: 547.05
  related item:
    title info:
      title: Springer eBooks
  related item:
    title info:
      title: Topics in Organometallic Chemistry, 22
  identifier: 9783540372103
  identifier: http://dx.doi.org/10.1007/11603818
  record info:
    record creation date: 100301
    record change date: 20151110231018.0
    record identifier: 978-3-540-37210-3