rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation
  name:
    name part: Matsumoto, Arimasa.
    role:
      role term: creator
    role:
      role term: author.
  name:
    name part: SpringerLink (Online service)
  type of resource: text
  origin info:
    place:
      place term: ja
    date issued: 2014
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: electronic
    form: electronic resource
    reformatting quality: access
    form: remote
    extent: XIII, 74 p. 105 illus. online resource.
  abstract: Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive, and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium, and rhodium. This thesis describes the first practical example of iron catalysis in the carbon–hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C–H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.
  table of contents: General Introduction -- Iron-Catalyzed Naphthalene Synthesis from Alkyne and Grignard Reagent -- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Grignard Reagent -- Iron-Catalyzed Phenanthrene Synthesis from Alkyne and Aryl Bromide Mediated by Metallic Magnesium -- Summary and Perspectives.
  note: by Arimasa Matsumoto.
  subject:
    topic: Chemistry
  subject:
    topic: Organometallic chemistry
  subject:
    topic: Metals
  subject:
    topic: Chemistry
  subject:
    topic: Organometallic Chemistry
  subject:
    topic: Metallic Materials
  classification: QD410-412.5
  classification: 547.05
  related item:
    title info:
      title: Springer eBooks
  related item:
    title info:
      title: Springer Theses, Recognizing Outstanding Ph.D. Research
  identifier: 9784431549284
  identifier: http://dx.doi.org/10.1007/978-4-431-54928-4
  record info:
    record creation date: 140707
    record change date: 20151204163729.0
    record identifier: 978-4-431-54928-4