rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Highly Luminescent Lanthanide Complexes with Specific Coordination Structures
  name:
    name part: Miyata, Kohei.
    role:
      role term: creator
    role:
      role term: author.
  name:
    name part: SpringerLink (Online service)
  type of resource: text
  origin info:
    place:
      place term: ja
    date issued: 2014
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: electronic
    form: electronic resource
    reformatting quality: access
    form: remote
    extent: XIII, 91 p. 52 illus., 21 illus. in color. online resource.
  abstract: This thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational frequency C–H units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency C–F and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point > 300°C) and strong-luminescent properties (emission quantum yield > 80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry.
  table of contents: General Introduction -- Luminescence Properties of Thermostable Lanthanide Coordination Polymers with Intermolecular Interactions -- Chameleon Luminophore for a Wide Range Temperature-Sensor Composed of Lanthanide Coordination Polymers -- Characteristic Structures and Photophysical Properties of Nona-coordinated Eu(III) Complexes with Tridentate Phosphine Oxides -- Photophysical Properties of Lanthanide Complexes with Asymmetric Dodecahedron Structures -- Solvent-dependent Luminescence of Octa-coordinated Eu(III) Complexes -- Summary.
  note: by Kohei Miyata.
  subject:
    topic: Chemistry
  subject:
    topic: Inorganic chemistry
  subject:
    topic: Physical chemistry
  subject:
    topic: Optical materials
  subject:
    topic: Electronic materials
  subject:
    topic: Chemistry
  subject:
    topic: Inorganic Chemistry
  subject:
    topic: Optical and Electronic Materials
  subject:
    topic: Physical Chemistry
  classification: QD146-197
  classification: 546
  related item:
    title info:
      title: Springer eBooks
  related item:
    title info:
      title: Springer Theses, Recognizing Outstanding Ph.D. Research
  identifier: 9784431549444
  identifier: http://dx.doi.org/10.1007/978-4-431-54944-4
  record info:
    record creation date: 140408
    record change date: 20151204163217.0
    record identifier: 978-4-431-54944-4