rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Design and Precise Synthesis of Thermoresponsive Polyacrylamides
  name:
    name part: Fuchise, Keita.
    role:
      role term: creator
    role:
      role term: author.
  name:
    name part: SpringerLink (Online service)
  type of resource: text
  origin info:
    place:
      place term: ja
    date issued: 2014
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: electronic
    form: electronic resource
    reformatting quality: access
    form: remote
    extent: XVIII, 81 p. 60 illus., 6 illus. in color. online resource.
  abstract: In this thesis, the author describes versatile and easy-to-use methods to control the properties of thermoresponsive polyacrylamides by developing novel synthetic methods for end-functionalized poly(N-isopropylacrylamide) (PNIPAM) and block copolymers of poly(N,N-diethylacrylamide) (PDEAA). The synthesis of various urea end-functionalized PNIPAMs was achieved by the atom transfer radical polymerization (ATRP) and the click reaction. The phase transition temperature of PNIPAM in water was controlled depending on the strength of the hydrogen bonding of the urea groups introduced at the chain end of the polymer. Novel living polymerization methods for N,N-dimethylacrylamide and N,N-diethylacrylamide were developed by group transfer polymerization (GTP) using a strong Brønsted acid as a precatalyst and an amino silyl enolate as an initiator. This process enabled the precise synthesis of PDEAA and its block copolymers—namely, thermoresponsive amphiphilic block copolymers and double-hydrophilic block copolymers.
  table of contents: General introduction -- Control of Thermoresponsive Properties of Urea End-Functionalized Poly(N-isopropylacrylamide) Based on the Hydrogen Bond Assisted Self-Assembly in Water -- Precise Synthesis of Poly(N,N-Dimethylacrylamide) by Group Transfer Polymerization Using a Strong Brønsted Acid and an Amino Silyl Enolate -- Facile Synthesis of Thermoresponsive Block Copolymers Bearing Poly(N,N-diethylacrylamide) Segment through Group Transfer Polymerization -- Conclusions.
  note: by Keita Fuchise.
  subject:
    topic: Chemistry
  subject:
    topic: Organic chemistry
  subject:
    topic: Polymers
  subject:
    topic: Chemistry
  subject:
    topic: Polymer Sciences
  subject:
    topic: Organic Chemistry
  classification: QD380-388
  classification: 541.2254
  related item:
    title info:
      title: Springer eBooks
  related item:
    title info:
      title: Springer Theses, Recognizing Outstanding Ph.D. Research
  identifier: 9784431550464
  identifier: http://dx.doi.org/10.1007/978-4-431-55046-4
  record info:
    record creation date: 140522
    record change date: 20151204183457.0
    record identifier: 978-4-431-55046-4