rdf-syntax-grammar
mods:
  schema location: http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
  title info:
    title: Functionalization of Carborane via Carboryne Intermediates
  name:
    name part: Zhao, Da.
    role:
      role term: creator
    role:
      role term: author.
  name:
    name part: SpringerLink (Online service)
  type of resource: text
  origin info:
    place:
      place term: si
    date issued: 2016
    issuance: monographic
  language:
    language term: eng
  physical description:
    form: electronic
    form: electronic resource
    reformatting quality: access
    form: remote
    extent: XVII, 170 p. 126 illus., 5 illus. in color. online resource.
  abstract: This thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal−organic frameworks, electronic devices and more. However, the limited number of efficient synthetic methods for obtaining functional carborane materials has restricted their applications. The methodologies established in this thesis represent simple, yet powerful strategies to assemble previously inaccessible, useful complex molecules, which will also have a significant impact on future synthetic, cluster and materials chemistry. Moreover, it discusses the first method for the in situ generation of electrophilic boron radical using photocatalysis. .
  table of contents: Introduction -- Regioselective Insertion of ο-Carborynes into α-C−H Bond of Tertiary Amines -- Synthesis of Carborane-Functionalized Heterocycles: Dearomative [2 + 2] Cycloaddition and sp2 C–H Insertion Reaction -- Reaction of ο-Carboryne with Nitrones: A Formal [5 + 2] Cycloaddition -- 1,3-Dehydro-ο-Carborane: Generation and Reaction with Arenes -- Ene Reaction of 1,3-Dehydro-ο-Carborane -- Cage Boron Arylation of ο-Carborane via Metal-Free, Visible-Light-Mediated Radical Coupling -- Conclusion -- Experimental Section.
  note: by Da Zhao.
  subject:
    topic: Chemistry
  subject:
    topic: Organic chemistry
  subject:
    topic: Physical chemistry
  subject:
    topic: Catalysis
  subject:
    topic: Chemistry
  subject:
    topic: Organic Chemistry
  subject:
    topic: Physical Chemistry
  subject:
    topic: Catalysis
  classification: QD415-436
  classification: 547
  related item:
    title info:
      title: Springer eBooks
  related item:
    title info:
      title: Springer Theses, Recognizing Outstanding Ph.D. Research
  identifier: 9789811015694
  identifier: http://dx.doi.org/10.1007/978-981-10-1569-4
  record info:
    record creation date: 160604
    record change date: 20160604081917.0
    record identifier: 978-981-10-1569-4