Metal Dihydrogen and σ-Bond Complexes Structure Theory and Reactivity /

• Κύριος συγγραφέας: Kubas, Gregory J. (Συγγραφέας)
• Συγγραφή απο Οργανισμό/Αρχή: SpringerLink (Online service)
• Μορφή: Ηλεκτρονική πηγή Ηλ. βιβλίο
• Γλώσσα: English
• Έκδοση: Boston, MA : Springer US, 2001.
• Σειρά: Modern Inorganic Chemistry
• Θέματα: Chemistry.; Inorganic chemistry.; Organometallic chemistry.; Physical chemistry.; Chemical engineering.; Organometallic Chemistry.; Physical Chemistry.; Inorganic Chemistry.; Industrial Chemistry/Chemical Engineering.

According to R.H. Crabtree, Metal Dihydrogen and sigma-Bond Complexes is described as `the definitive account of twentieth-century work in the area of sigma complexation'. It covers not only Kubas' discovery of dihydrogen coordination and the study of its structure and general properties b...

Πίνακας περιεχομένων:

• Background and Discovery of Dihydrogen Coordination
• Synthesis and General Properties of Dihydrogen Complexes
• Bonding and Activation of Dihydrogen and ? Ligands: Theory versus Experiment
• Structural and NMR Studies of Dihydrogen Complexes
• Intramolecular Dynamics of Dihydrogen-hydride Ligand Systems: Hydrogen Rotation, Exchange, and Quantum-mechanical Effects
• Thermodynamics, Kinetics, and Isotope Effects of the Binding and Cleavage of ? Ligands versus Classical Ligands
• Vibrational Studies of Coordinated Dihydrogen
• Reactions and Acidity of Dihydrogen Complexes
• Activation of Hydrogen and Related Small Molecules by Metalloenzymes and Sulfur Ligand Systems
• Coordination and Activation of Si-H, Ge-H, and Sn-H Bonds
• C-H Bond Coordination and Activation
• Coordination and Activation of B-H and Other X-H and X-Y Bonds.