Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands

• Main Author: Ghana, Priyabrata (Author, http://id.loc.gov/vocabulary/relators/aut)
• Corporate Author: SpringerLink (Online service)
• Format: Electronic eBook
• Language: English
• Published: Cham : Springer International Publishing : Imprint: Springer, 2019.
• Edition: 1st ed. 2019.
• Series: Springer Theses, Recognizing Outstanding Ph.D. Research,
• Subjects: Organometallic chemistry .; Inorganic chemistry.; Spectroscopy.; Organometallic Chemistry.; Inorganic Chemistry.; Spectroscopy/Spectrometry.

This book explores the development of the first open-shell heavier tetrylidyne complexes featuring a tetrel-centered unpaired electron, and unprecedented metallatetrylidynes containing a multiply-bonded, linear-coordinated single heavier tetrel atom embedded between two metal centers. The chemistry...

Table of Contents:

• Introduction
• Closed shell heavier tetrylidyne complexes of group 6 metals
• Open-shell heavier tetrylidyne complexes of group 6 transition metals
• Germylidyne mediated C-C coupling reaction of isonitriles - formation of an N-heterocyclic germylene
• A new method for the synthesis of manganese tetrylidyne complexes
• An open-shell manganese stannylidyne comprising of a tin-centered unpaired electron
• µ-Ylido complexes
• Chemistry of the metallatetrylidyne complexes
• Plumbylidyne transfer reaction
• Access to the first NHC-stabilized disilavinylidene
• Summary and Outlook
• Experimental Section.