Synthesis and Original Reactivity of Copper and Gold Complexes σ-Bond Coordination, Oxidative Addition, Migratory Insertion /

• Κύριος συγγραφέας: Joost, Maximilian (Συγγραφέας)
• Συγγραφή απο Οργανισμό/Αρχή: SpringerLink (Online service)
• Μορφή: Ηλεκτρονική πηγή Ηλ. βιβλίο
• Γλώσσα: English
• Έκδοση: Cham : Springer International Publishing : Imprint: Springer, 2015.
• Σειρά: Springer Theses, Recognizing Outstanding Ph.D. Research,
• Θέματα: Chemistry.; Chemoinformatics.; Organometallic chemistry.; Physical chemistry.; Organometallic Chemistry.; Physical Chemistry.; Computer Applications in Chemistry.

This thesis addresses the coordination chemistry and reactivity of copper and gold complexes with a focus on the elucidation of (i) the metal-mediated activation of σ-bonds and (ii) the migratory insertion reaction. Both processes are of considerable importance in organometallic chemistry, but remai...

Πίνακας περιεχομένων:

• General Introduction
• Copper: σ-SiH Coordination to Cu(I)
• Fundamental Elementary Steps in Gold Chemistry
• Gold: Migratory Insertion at Au(I)
• Gold: Oxidative Addition to Au(I)
• General Conclusion and Perspective
• Appendix: Crystallographic Data.