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03015nam a22004815i 4500 |
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978-3-319-51807-7 |
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DE-He213 |
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20170214073329.0 |
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170214s2017 gw | s |||| 0|eng d |
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|a 9783319518077
|9 978-3-319-51807-7
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|a 10.1007/978-3-319-51807-7
|2 doi
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|a QD410-412.5
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|a SCI013040
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|a 547.05
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|a Hadlington, Terrance John.
|e author.
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|a On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes
|h [electronic resource] /
|c by Terrance John Hadlington.
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|a Cham :
|b Springer International Publishing :
|b Imprint: Springer,
|c 2017.
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|a XIX, 243 p. 170 illus., 59 illus. in color.
|b online resource.
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|a text
|b txt
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|a computer
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|a online resource
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|a text file
|b PDF
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|a Springer Theses, Recognizing Outstanding Ph.D. Research,
|x 2190-5053
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|a General Introduction -- The Development of Extremely Bulky Amide Ligands and their Application to the Synthesis of Group 14 Element(II) Halides -- Synthesis and Reactivity of Heavier Alkyne Analogues Stabilised by Extremely Bulky Amide Ligands -- Reactivity of Low-Coordinate Group 14 Element(II) Hydride Complexes -- Stoichiometric Reactivity and Catalytic Applications of Heavier Tetrelene Derivatives -- The Use of a Bulky Boryl-Substituted Amide Ligand in Low-Oxidation State Group 14 Element Chemistry.
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|a This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal–metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry.
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|a Chemistry.
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|a Inorganic chemistry.
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|a Organometallic chemistry.
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|a Catalysis.
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|a Chemistry.
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|a Organometallic Chemistry.
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|a Catalysis.
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|a Inorganic Chemistry.
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|a SpringerLink (Online service)
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|t Springer eBooks
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|i Printed edition:
|z 9783319518060
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|a Springer Theses, Recognizing Outstanding Ph.D. Research,
|x 2190-5053
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|u http://dx.doi.org/10.1007/978-3-319-51807-7
|z Full Text via HEAL-Link
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|a ZDB-2-CMS
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|a Chemistry and Materials Science (Springer-11644)
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