Magnetic Functions Beyond the Spin-Hamiltonian

• Corporate Author: SpringerLink (Online service)
• Other Authors: Mingos, D. M. P. (Editor)
• Format: Electronic eBook
• Language: English
• Published: Berlin, Heidelberg : Springer Berlin Heidelberg, 2006.
• Series: Structure and Bonding, 117
• Subjects: Chemistry.; Inorganic chemistry.; Chemistry, Physical and theoretical.; Magnetism.; Magnetic materials.; Inorganic Chemistry.; Theoretical and Computational Chemistry.; Magnetism, Magnetic Materials.

Using the spin-Hamiltonian formalism the magnetic parameters are introduced through the components of the Lambda-tensor involving only the matrix elements of the angular momentum operator. The energy levels for a variety of spins are generated and the modeling of the magnetization, the magnetic susc...

Table of Contents:

• R. Boca: Magnetic Parameters and Magnetic Functions in Mononuclear Complexes Beyond the Spin-Hamiltonian Formalism: Introduction
• Energy Levels of Multi-Term Systems
• Modeling the Magnetic Parameters
• Calculations of Energy Levels and Magnetic Parameters
• Empirical Magnetic Parameters
• Conclusions
• References
• Appendix A: Spectroscopic Constants, Coefficients and Matrix Elements
• Appendix B: Elements of the Irreducible Tensor Approach
• Appendix C: Classification of Crystal-Field Terms and Multiplets
• Appendix D: Calculated Energy Levels and Magnetic Parameters.