Hydroboration and Organic Synthesis 9-Borabicyclo[3.3.1]nonane (9-BBN) /

• Κύριος συγγραφέας: Dhillon, Ranjit S. (Συγγραφέας)
• Συγγραφή απο Οργανισμό/Αρχή: SpringerLink (Online service)
• Μορφή: Ηλεκτρονική πηγή Ηλ. βιβλίο
• Γλώσσα: English
• Έκδοση: Berlin, Heidelberg : Springer Berlin Heidelberg, 2007.
• Θέματα: Chemistry.; Organic chemistry.; Medicinal chemistry.; Biochemistry.; Organic Chemistry.; Medicinal Chemistry.; Biochemistry, general.

9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-...

Πίνακας περιεχομένων:

• General Remarks
• Preparation and Properties
• Kinetic Studies
• Hydroboration
• Synthesis of Alcohols
• Synthesis of Aldehydes and Ketones
• Synthesis of Carboxylic Acids
• Synthesis of Esters
• Synthesis of Nitriles
• Synthesis of (E)-?,?-Unsaturated Amides
• Synthesis of Amines
• Synthesis of Halides
• Synthesis of Dialkylsulfides
• Synthesis of Thiophene Oligomers
• Synthesis of Cyclopropanes and Cyclobutanes
• Synthesis of Borinanes
• Synthesis and Transformations of Butterflyboranes: cis-Bicyclo[3.3.0]oct-1-yldialkylboranes
• Synthesis of ?-Bromoboranes
• Synthesis of Borinates
• Synthesis and Transformation of Polymers
• Synthesis of Alkali Metal 9-Boratabicyclo[3.3.1] nonane (Li, K, and Na 9-BBNH)
• Synthesis of B-R-9-BBN Not Available via Hydroboration
• Synthesis of Unsaturated Compounds
• Reduction
• Asymmetric Reduction
• Cleavage of Ethers
• trans-Metalation
• Separation of Isomers
• Diels-Alder Reaction
• Suzuki Reaction
• Miscellaneous Reactions.