Directed Metallation

• Corporate Author: SpringerLink (Online service)
• Other Authors: Chatani, Naoto (Editor)
• Format: Electronic eBook
• Language: English
• Published: Berlin, Heidelberg : Springer Berlin Heidelberg, 2007.
• Series: Topics in Organometallic Chemistry, 24
• Subjects: Chemistry.; Inorganic chemistry.; Organometallic chemistry.; Medicinal chemistry.; Catalysis.; Organometallic Chemistry.; Inorganic Chemistry.; Medicinal Chemistry.

Directed metalation is recognized as one of the most useful methodologies for the regio- and stereoselective generation of organometallic species, the generation of which necessarily leads to the selective formation of organic products. Cyclometalation using Li, Mn, and Pd, and directed hydrometalat...

Table of Contents:

• Catalytic Addition of C?–?H Bonds to C?–?C Multiple Bonds
• Chelation-Assisted Arylation via C–H Bond Cleavage
• Catalytic Arylation and Vinylation Reactions Directed by Anionic Oxygen Functions via Cleavage of C?–?H and C?–?C Bonds
• Chelate-Directed Oxidative Functionalization of Carbon–Hydrogen Bonds: Synthetic Applications and Mechanistic Insights
• Directed C?–?C Bond Activation by Transition Metal Complexes
• Directed Rhodium-Catalyzed Hydroformylation of Alkenes
• Directed Mizoroki–Heck Reactions.