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03155nam a22004815i 4500 |
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978-3-642-23129-2 |
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|a 9783642231292
|9 978-3-642-23129-2
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|a 10.1007/978-3-642-23129-2
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|a 543.2-543.8
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|a Simpson, Matthew J.
|e author.
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|a Two Studies in Gas-Phase Ion Spectroscopy
|h [electronic resource] :
|b Vacuum-Ultraviolet Negative Photoion Spectroscopy and Ion-Molecule Reaction Kinetics /
|c by Matthew J. Simpson.
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|a Berlin, Heidelberg :
|b Springer Berlin Heidelberg,
|c 2012.
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|a XIV, 162 p.
|b online resource.
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|a text
|b txt
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|a online resource
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|b PDF
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|a Springer Theses
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|a Introduction and background information -- The experiments.- Vacuum-ultraviolet negative photoion spectroscopy of SF6, CF4 and SF5CF3 -- Vacuum-ultraviolet negative photoion spectroscopy of CF3Cl, CF3Br and CF3I -- Vacuum-ultraviolet negative photoion spectroscopy of SF5Cl -- Vacuum-ultraviolet negative photoion spectroscopy of small polyatomic molecules -- The reactions of CFn+ (n = 1-3) with C2H4, C2H3F, CH2CF2 and C2HF3 -- The reactions of C2F4+ with C2H4, C2H3F, CH2CF2 and C2HF3 -- Reactions of OH-, O-, CF3-, F- and O2- with C2H4, C2H3F, CH2CF2, C2HF3 and C2F4 .
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|a In this thesis Matthew Simpson reports two areas of work in gas ion spectroscopy, each investigation in itself worthy of a PhD. The first study uses tunable vacuum-ultraviolet radiation from a synchrotron to identify negative ions from twenty four photoexcited polyatomic molecules in the gas phase. From these experiments, Matthew collects a vast amount of data and summarises and reviews ion-pair formation from polyatomic molecules. The second study is on selected ion flow tube mass spectrometry. Matthew investigates the reactions of cations and anions with ethene, monofluoroethene, 1,1-difluoroethene and tetrafluoroethene. In this study Matthew tries to explain why certain products are formed preferentially over other products at a microscopic level of understanding. The data recorded in this thesis form the most comprehensive collection of information about anion formation and are the basis of a review and numerous articles in specialist journals.
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|a Chemistry.
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|a Spectroscopy.
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|a Physical chemistry.
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|a Microscopy.
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|a Chemistry.
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|a Spectroscopy/Spectrometry.
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|a Spectroscopy and Microscopy.
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|a Physical Chemistry.
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|a SpringerLink (Online service)
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|t Springer eBooks
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|i Printed edition:
|z 9783642231285
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|a Springer Theses
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|u http://dx.doi.org/10.1007/978-3-642-23129-2
|z Full Text via HEAL-Link
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|a ZDB-2-CMS
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|a Chemistry and Materials Science (Springer-11644)
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