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03356nam a22005535i 4500 |
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978-3-642-39115-6 |
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DE-He213 |
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20151030081024.0 |
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130804s2013 gw | s |||| 0|eng d |
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|a 9783642391156
|9 978-3-642-39115-6
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|a 10.1007/978-3-642-39115-6
|2 doi
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|a SCI013060
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|a 541.395
|2 23
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|a Wu, Peng.
|e author.
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|a MWW-Type Titanosilicate
|h [electronic resource] :
|b Synthesis, Structural Modification and Catalytic Applications to Green Oxidations /
|c by Peng Wu, Hao Xu, Le Xu, Yueming Liu, Mingyuan He.
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|a Berlin, Heidelberg :
|b Springer Berlin Heidelberg :
|b Imprint: Springer,
|c 2013.
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|a VIII, 125 p. 79 illus., 25 illus. in color.
|b online resource.
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|a text
|b txt
|2 rdacontent
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|a computer
|b c
|2 rdamedia
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|a online resource
|b cr
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|a text file
|b PDF
|2 rda
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|a SpringerBriefs in Molecular Science,
|x 2191-5407
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|a Introduction -- Synthesis of Ti-MWW zeolite -- Post-synthesis modification of Ti-MWW: a door to diversity -- Catalytic properties of Ti-MWW in selective oxidation reactions -- Conclusions and Prospects.
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|a This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.
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|a Chemistry.
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|a Physical chemistry.
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|a Chemical engineering.
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|a Catalysis.
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|a Environmental chemistry.
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|a Chemistry.
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|a Catalysis.
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|a Environmental Chemistry.
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|a Industrial Chemistry/Chemical Engineering.
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|a Physical Chemistry.
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|a Xu, Hao.
|e author.
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|a Xu, Le.
|e author.
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|a Liu, Yueming.
|e author.
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|a He, Mingyuan.
|e author.
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|a SpringerLink (Online service)
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|t Springer eBooks
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|i Printed edition:
|z 9783642391149
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|a SpringerBriefs in Molecular Science,
|x 2191-5407
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4 |
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|u http://dx.doi.org/10.1007/978-3-642-39115-6
|z Full Text via HEAL-Link
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|a ZDB-2-CMS
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|a Chemistry and Materials Science (Springer-11644)
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