Pressure-Induced Phase Transitions in AB2X4 Chalcogenide Compounds

This book on pressure-induced phase transitions in AB2X4 chalcogenide compounds deals with one important AmBnXp material. The interest in these materials is caused by their properties. The results are discussed for three main groups of structural families: cubic-spinel structures, defective tetragon...

Πλήρης περιγραφή

Λεπτομέρειες βιβλιογραφικής εγγραφής
Συγγραφή απο Οργανισμό/Αρχή: SpringerLink (Online service)
Άλλοι συγγραφείς: Manjon, Francisco Javier (Επιμελητής έκδοσης), Tiginyanu, Ion (Επιμελητής έκδοσης), Ursaki, Veaceslav (Επιμελητής έκδοσης)
Μορφή: Ηλεκτρονική πηγή Ηλ. βιβλίο
Γλώσσα:English
Έκδοση: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 2014.
Σειρά:Springer Series in Materials Science, 189
Θέματα:
Διαθέσιμο Online:Full Text via HEAL-Link
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245 1 0 |a Pressure-Induced Phase Transitions in AB2X4 Chalcogenide Compounds  |h [electronic resource] /  |c edited by Francisco Javier Manjon, Ion Tiginyanu, Veaceslav Ursaki. 
264 1 |a Berlin, Heidelberg :  |b Springer Berlin Heidelberg :  |b Imprint: Springer,  |c 2014. 
300 |a XIII, 243 p. 121 illus., 33 illus. in color.  |b online resource. 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
347 |a text file  |b PDF  |2 rda 
490 1 |a Springer Series in Materials Science,  |x 0933-033X ;  |v 189 
505 0 |a Introduction -- Part I Spinel-Structured AB Chalcogenide Compounds -- Part II Ordered-Vacancy AB Chalcogenide Compounds -- Part III Chalcogenide Compounds with other Types of Structures. 
520 |a This book on pressure-induced phase transitions in AB2X4 chalcogenide compounds deals with one important AmBnXp material. The interest in these materials is caused by their properties. The results are discussed for three main groups of structural families: cubic-spinel structures, defective tetragonal structures, and other structures like layered and wurtzite-type modifications. A systematic analysis of the behavior of cubic (spinel), tetragonal (defect chalcopyrites and stannites) and other crystal modifications of AB2X4 compounds under hydrostatic pressure is performed. The behavior of AIIAl2S4, AIIGa2S4, AIIAl2Se4 and AIIGa2Se4 compounds with defective tetragonal structures, compounds with layered and wurtzite structures under hydrostatic pressure and the pressure dependence of the band gap, lattice parameters, interatomic distances, vibrational modes and pressure-induced phase transitions is discussed. Many of these compounds,  except oxide spinels, undergo a pressure-induced phase transition towards the rocksalt-type structure. The phase transition is preceded by disorder in the cation sublattice. The dependence of the transition pressure to the rocksalt-type structure as a function of the compound ionicity and the size criterion is analyzed.  At high pressures, all ordered-vacancy compounds are found to exhibit a band anticrossing between several conduction bands that leads to a strong decrease of its pressure coefficient and consequently to a strong non-linear pressure dependence of the direct bandgap energy. Theoretical studies of phase transitions in several ordered-vacancy compounds reveal that the existence of ordered vacancies alter the cation-anion bond distances and their compressibilities. The book is written for students, Ph D. students and specialists in materials science, phase transitions and new materials. 
650 0 |a Materials science. 
650 0 |a Semiconductors. 
650 0 |a Physics. 
650 0 |a Microwaves. 
650 0 |a Optical engineering. 
650 0 |a Optical materials. 
650 0 |a Electronic materials. 
650 1 4 |a Materials Science. 
650 2 4 |a Optical and Electronic Materials. 
650 2 4 |a Semiconductors. 
650 2 4 |a Microwaves, RF and Optical Engineering. 
650 2 4 |a Applied and Technical Physics. 
700 1 |a Manjon, Francisco Javier.  |e editor. 
700 1 |a Tiginyanu, Ion.  |e editor. 
700 1 |a Ursaki, Veaceslav.  |e editor. 
710 2 |a SpringerLink (Online service) 
773 0 |t Springer eBooks 
776 0 8 |i Printed edition:  |z 9783642403668 
830 0 |a Springer Series in Materials Science,  |x 0933-033X ;  |v 189 
856 4 0 |u http://dx.doi.org/10.1007/978-3-642-40367-5  |z Full Text via HEAL-Link 
912 |a ZDB-2-CMS 
950 |a Chemistry and Materials Science (Springer-11644)