Development of Novel Hydrogen-Bond Donor Catalysts

• Κύριος συγγραφέας: Inokuma, Tsubasa (Συγγραφέας)
• Συγγραφή απο Οργανισμό/Αρχή: SpringerLink (Online service)
• Μορφή: Ηλεκτρονική πηγή Ηλ. βιβλίο
• Γλώσσα: English
• Έκδοση: Tokyo : Springer Japan : Imprint: Springer, 2013.
• Σειρά: Springer Theses, Recognizing Outstanding Ph.D. Research,
• Θέματα: Chemistry.; Organic chemistry.; Medicinal chemistry.; Catalysis.; Organic Chemistry.; Medicinal Chemistry.

This work describes novel, effective hydrogen-bond (HB) donor catalysts based on a known bifunctional tertiary amine-thiourea, a privileged structure, which has been proven to be one of the most widely used organocatalysts. These HB donor catalysts derived from quinazoline and benzothiadiazine were...

Πίνακας περιεχομένων:

• Introduction
• Development of HB donor catalysts
• Development and properties of novel HB donor catalysts
• Asymmetric Michael addition to alpha,beta-unsaturated imides catalyzed by HB donors
• Asymmetric Hydrazination of activated methylene compounds catalyzed by HB donors
• Development of hydroxy thiourea catalysts
• Asymmetric Michael addition of gamma-hydroxyenones and alkenylboronic acids
• Asymmetric Petasis Reaction of N-aryl-alpha-iminoamides and Alkenylboronates
• Conclusion.