Group Theory Applied to Chemistry

• Κύριος συγγραφέας: Ceulemans, Arnout Jozef (Συγγραφέας)
• Συγγραφή απο Οργανισμό/Αρχή: SpringerLink (Online service)
• Μορφή: Ηλεκτρονική πηγή Ηλ. βιβλίο
• Γλώσσα: English
• Έκδοση: Dordrecht : Springer Netherlands : Imprint: Springer, 2013.
• Σειρά: Theoretical Chemistry and Computational Modelling,
• Θέματα: Chemistry.; Inorganic chemistry.; Chemistry, Physical and theoretical.; Crystallography.; Theoretical and Computational Chemistry.; Inorganic Chemistry.

 Chemists are used to the operational definition of symmetry, which crystallographers introduced long before the advent of quantum mechanics. The ball-and-stick models of molecules naturally exhibit the symmetrical properties of macroscopic objects. However, the practitioner of quantum chemistry and molecular modeling is not concerned with balls and sticks, but with subatomic particles: nuclei and electrons. This textbook introduces the subtle metaphors which relate our macroscopic understanding of symmetry to the molecular world. It gradually explains how bodily rotations and reflections, which leave all inter-particle distances unaltered, affect the study of molecular phenomena that depend only on these internal distances. It helps readers to acquire the skills to make use of the mathematical tools of group theory for whatever chemical problems they are confronted with in the course of their own research. 

 Operations -- Function spaces and matrices -- Groups -- Representations -- What has quantum chemistry got to do with it? -- Interactions -- Spherical symmetry and spins.