Functionalization of Carborane via Carboryne Intermediates

• Κύριος συγγραφέας: Zhao, Da (Συγγραφέας)
• Συγγραφή απο Οργανισμό/Αρχή: SpringerLink (Online service)
• Μορφή: Ηλεκτρονική πηγή Ηλ. βιβλίο
• Γλώσσα: English
• Έκδοση: Singapore : Springer Singapore : Imprint: Springer, 2016.
• Σειρά: Springer Theses, Recognizing Outstanding Ph.D. Research,
• Θέματα: Chemistry.; Organic chemistry.; Physical chemistry.; Catalysis.; Organic Chemistry.; Physical Chemistry.

This thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal−organic frameworks, electronic devices and mo...

Πίνακας περιεχομένων:

• Introduction
• Regioselective Insertion of ο-Carborynes into α-C−H Bond of Tertiary Amines
• Synthesis of Carborane-Functionalized Heterocycles: Dearomative [2 + 2] Cycloaddition and sp2 C–H Insertion Reaction
• Reaction of ο-Carboryne with Nitrones: A Formal [5 + 2] Cycloaddition
• 1,3-Dehydro-ο-Carborane: Generation and Reaction with Arenes
• Ene Reaction of 1,3-Dehydro-ο-Carborane
• Cage Boron Arylation of ο-Carborane via Metal-Free, Visible-Light-Mediated Radical Coupling
• Conclusion
• Experimental Section.