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03223nam a22005295i 4500 |
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978-981-10-6135-6 |
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DE-He213 |
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20170808182815.0 |
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170808s2017 si | s |||| 0|eng d |
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|a 9789811061356
|9 978-981-10-6135-6
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|a 10.1007/978-981-10-6135-6
|2 doi
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|a Imoto, Kenta.
|e author.
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|a Multifunctional Molecular Magnets Based on Octacyanidometalates
|h [electronic resource] /
|c by Kenta Imoto.
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|a Singapore :
|b Springer Singapore :
|b Imprint: Springer,
|c 2017.
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| 300 |
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|a XIII, 89 p. 64 illus., 38 illus. in color.
|b online resource.
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|a text
|b txt
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|a computer
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|a online resource
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|a text file
|b PDF
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|a Springer Theses, Recognizing Outstanding Ph.D. Research,
|x 2190-5053
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|a 1. Introduction -- 2. Light-induced Spin-crossover Magnetism in an Iron Octacyanidoniobate-based Assembly -- 3. Two-step Spin-crossover and Photo-induced Spin-crossover in an Iron Octacyanidoniobate-based Assembly -- 4. Observation of Coexistence of Super-ionic Conductivity and Metamagnetism in a Manganese Octacyanidoniobate-based Assembly -- 5. Summary and Perspective.
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|a This thesis demonstrates the novel magnetic functionalities in cyanido-bridged metal assemblies, and as such appeals to readers in the field of materials science. The utilization of octacyanidometalates as building blocks enables the observation of (i) photo-induced magnetization due to a light-induced spin-crossover in an iron octacyanidoniobate-based assembly, (ii) photo-induced magnetization with a two-step spin-crossover behavior in an iron octacyanidoniobate-based material, and (iii) the coexistence of super-ionic conductivity and metamagnetism in a manganese-octacyanoniobate system. These multi-functionalities are achieved by incorporating a spin-crossover moiety or a hydrogen-bonding network into a cyanido-bridged network structure with a strong magnetic interaction. In particular, in light-induced spin-crossover magnets, a magnetically non-ordered state can be altered to a magnetically ordered state by photo-irradiation, which is one of the attractive mechanisms for novel optical switching devices.
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| 650 |
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|a Chemistry.
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| 650 |
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|a Inorganic chemistry.
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| 650 |
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|a Physical chemistry.
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| 650 |
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|a Magnetism.
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| 650 |
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|a Magnetic materials.
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|a Optical materials.
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|a Electronic materials.
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|a Chemistry.
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|a Inorganic Chemistry.
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|a Magnetism, Magnetic Materials.
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| 650 |
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|a Optical and Electronic Materials.
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| 650 |
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|a Physical Chemistry.
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| 710 |
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|a SpringerLink (Online service)
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|t Springer eBooks
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|i Printed edition:
|z 9789811061349
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| 830 |
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|a Springer Theses, Recognizing Outstanding Ph.D. Research,
|x 2190-5053
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|u http://dx.doi.org/10.1007/978-981-10-6135-6
|z Full Text via HEAL-Link
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|a ZDB-2-CMS
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|a Chemistry and Materials Science (Springer-11644)
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