Sample preparation for trace element analysis /
Following the collection of a sample, every analytical chemist will agree that its subsequent preservation and processing are of paramount importance. The availability of high performance analytical instrumentation has not diminished this need for careful selection of appropriate pretreatment method...
| Άλλοι συγγραφείς: | , |
|---|---|
| Μορφή: | Ηλ. βιβλίο |
| Γλώσσα: | English |
| Έκδοση: |
Amsterdam ; Boston :
Elsevier,
2003.
|
| Έκδοση: | 1st ed. |
| Σειρά: | Comprehensive analytical chemistry ;
v. 41. |
| Θέματα: | |
| Διαθέσιμο Online: | Full Text via HEAL-Link |
Πίνακας περιεχομένων:
- Cover
- Contents
- Contributors to Vol XLI
- Volumes in the Series
- Series Editor's Preface
- Preface
- Acronyms
- Chapter 1. Sampling and sample preservation for trace element analysis
- 1.1 Introduction
- 1.2 Preliminary considerations
- 1.3 Types of samples
- 1.4 Planning the sampling operation
- 1.5 Statistical sampling
- 1.6 Sample handling and preservation during collection, transport, and storage
- 1.7 Quality assurance in sampling [24,25]
- 1.8 Glossary
- References
- Selected bibliography
- Chapter 2. Sources of analyte contamination and loss during the analytical process
- 2.1 Introduction
- 2.2 Contamination
- 2.3 Losses
- 2.4 Sampling
- 2.5 Storage
- 2.6 Drying and homogenisation
- 2.7 Dilution, dissolution and digestion
- 2.8 Separation and preconcentration
- 2.9 Element measurement
- References
- Chapter 3. Calibration approaches for trace element determination
- 3.1 Introduction
- 3.2 Basic assumptions and some terminology
- 3.3 Selection of the calibration approach
- 3.4 Statistical evaluation of recovery data
- 3.5 Linear regression
- 3.6 External calibration
- 3.7 Method of standard additions
- 3.8 Internal standardization
- 3.9 Isotope dilution
- Acknowledgements
- References
- Chapter 4. Stated references for ensuring traceability of trace element analysis
- 4.1 Introduction
- 4.2 Meaning of traceability for chemical measurements
- 4.3 SI units
- 4.4 Documented standards
- 4.5 Reference methods
- 4.6 Reference materials
- 4.7 Specimen banking
- 4.8 Proficiency testing
- 4.9 Real-case achievement of traceability of trace element analysis
- 4.10 Conclusions
- References
- Chapter 5. Detection methods for the quantitation of trace elements
- 5.1 Introduction
- 5.2 Classical methods
- 5.3 Flame spectrometry
- 5.4 Electrothermal AAS
- 5.5 Inductively coupled plasma-atomic emission spectrometry
- 5.6 Inductively coupled plasma-mass spectrometry
- 5.7 Atomic Fluorescence spectrometry
- 5.8 Other atomic absorption, emission and Fluorescence methods of detection
- 5.9 Secondary ion mass spectrometry
- 5.10 Glow discharge mass spectrometry
- 5.11 X-ray Fluorescence spectrometry
- 5.12 UV/Visible spectrophotometric and chemiluminescence techniques
- 5.13 Electrochemical methods
- References
- SECTION
- 1: DIGESTION AND EXTRACTION APPROACHES
- Chapter 6. Wet digestion methods
- 6.1 Introduction and brief history
- 6.2 Nomenclature
- 6.3 Bibliography
- 6.4 Reagents and vessel materials for wet digestion procedures
- 6.5 Wet acid digestion (decomposition and dissolution) procedures
- 6.6 Conclusions and future trends
- References
- Chapter 7. Dry ashing
- 7.1 General considerations
- 7.2 Why dry ashing?
- 7.3 Oxidation process and dissolution of the residue
- 7.4 Methodology
- 7.5 Particular cases of arsenic and selenium
- 7.6 Conclusions
- References
- Chapter 8 &
- Sampling and sample preservation for trace element analysis / Byron Kratochvil
- Sources of analyte contamination and loss during the analytical process / G. Knapp, P. Schramel
- Calibration approaches for trace element determination / Douglas C Baxter, Ilia Rodushkin
- Stated references for ensuring traceability of trace element analysis / Ph Quevauviller
- Detection methods for the quantitation of trace elements / Les Ebdon, Andrew S. Fisher, Maria Betti, Maurice Leroy
- Wet digestion methods / Henryk Matusiewicz
- Dry ashing / Michel Hoenig
- Microwave-based extraction / Edward E King, David Barclay
- Fusion and fluxes / Fernand Claisse
- Supercritical fluid extraction / R Alzaga, S Dı́ez, J.M Bayona
- Accelerated solvent extraction of organometallic and inorganic compounds / John L Ezzell
- Sonication as a sample preparation method for elemental analysis / Kevin Ashley
- Solid phase microextraction as a tool for trace element determination / Zoltán Mester, Ralph Sturgeon
- Solid-phase extraction / Valérie Camel
- Chelation solvent extraction for separation of metal ions / Hideyuki Itabashi, Taketoshi Nakahara
- Cryogenic trapping for speciation analysis / M.P Pavageau, E Krupp, A de Diego, C Pécheyran, O.F.X Donard
- Biotrapping as an alternative to metal preconcentration and speciation / Yolanda Madrid, Carmen Cámara
- Membrane extraction / Jan Åke Jönsson, Lennart Mathiasson
- Derivatization and vapor generation methods for trace element analysis and speciation / Yong Cai
- Laser ablation sampling / Richard E Russo, David P Baldwin
- Flow injection techniques for sample pretreatment / Zhao-Lun Fang
- Automation of sample preparation / M.D Luque de Castro, J.L Luque Garcı́a
- Sample preparation for crude oil, petroleum products and polymers / Robert I Botto
- Sample preparation of geological samples, soils and sediments / Philip J Potts, Philip Robinson
- Sample preparation for food analysis / Milan Ihnat
- The determination of trace elements in water / Scott N Willie
- Aerosol sampling and sample preparation for elemental analysis / József Hlavay
- Sample preparation for industrial waste analysis / Peter Drouin, Ray E Clement
- Sample preparation for semiconductor materials / Katsu Kawabata, Yoko Kishi, Fuhe Li, Scott Anderson
- Sampling and sample treatment in the analysis of organotin compounds in environmental samples / Roberto Morabito
- Sample preparation for arsenic speciation / Walter Goessler, Doris Kuehnelt
- Sample preparation for speciation of selenium / Claudia Ponce de Leon, Anne P Vonderheide, Joseph A Caruso
- Sample preparation for mercury speciation / Holger Hintelmann
- Sample preparation for speciation of lead / Freddy C Adams, Monika Heisterkamp
- Sample preparation for chromium speciation / Miguel de la Guardia, Angel Morales-Rubio
- Sample preparation for metal-based drugs / R.R Barefoot
- Sample preparation for speciation analysis for metallobiomolecules / Joanna Szpunar, Brice Bouyssiere, Ryszard Lobinski
- Sample preparation for the analysis of volatile metal species / Jörg Feldmann
- Sequential extraction / Angels Sahuquillo, Gemma Rauret.
