The chemical bond : chemical bonding across the periodic table /

"A unique overview of the different kinds of chemical bonds that can be found in the periodic table, from the main-group elements to transition elements, lanthanides and actinides. It takes into account the many developments that have taken place in the field over the past few decades due to th...

Πλήρης περιγραφή

Λεπτομέρειες βιβλιογραφικής εγγραφής
Άλλοι συγγραφείς: Frenking, G. (Gernot) (Επιμελητής έκδοσης), Shaik, Sason S., 1943- (Επιμελητής έκδοσης)
Μορφή: Ηλ. βιβλίο
Γλώσσα:English
Έκδοση: Weinheim, Germany : Wiley-VCH Verlag GmbH & Co, 2014.
Θέματα:
Διαθέσιμο Online:Full Text via HEAL-Link
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049 |a MAIN 
245 0 4 |a The chemical bond :  |b chemical bonding across the periodic table /  |c edited by Gernot Frenking and Sason Shaik. 
264 1 |a Weinheim, Germany :  |b Wiley-VCH Verlag GmbH & Co,  |c 2014. 
264 4 |c ©2014 
300 |a 1 online resource (568 pages) :  |b illustrations 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
504 |a Includes bibliographical references at the end of each chapters and index. 
588 0 |a Online resource; title from PDF title page (ebrary, viewed May 31, 2014). 
505 0 |a The Chemical Bond; Contents; Preface; List of Contributors; Chapter 1 Chemical Bonding of Main-Group Elements; 1.1 Introduction and Definitions; 1.2 The Lack of Radial Nodes of the 2p Shell Accounts for Most of the Peculiarities of the Chemistry of the 2p-Elements; 1.2.1 High Electronegativity and Small Size of the 2p-Elements; 1.2.1.1 Hybridization Defects; 1.2.2 The Inert-Pair Effect and its Dependence on Partial Charge of the Central Atom; 1.2.3 Stereo-Chemically Active versus Inactive Lone Pairs; 1.2.4 The Multiple-Bond Paradigm and the Question of Bond Strengths. 
505 8 |a 1.2.5 Influence of Hybridization Defects on Magnetic-Resonance Parameters1.3 The Role of the Outer d-Orbitals in Bonding; 1.4 Secondary Periodicities: Incomplete-Screening and Relativistic Effects; 1.5 ""Honorary d-Elements"": the Peculiarities of Structure and Bonding of the Heavy Group 2 Elements; 1.6 Concluding Remarks; References; Chapter 2 Multiple Bonding of Heavy Main-Group Atoms; 2.1 Introduction; 2.2 Bonding Analysis of Diatomic Molecules E2 (E = N -- Bi); 2.3 Comparative Bonding Analysis of N2 and P2 with N4 and P4; 2.4 Bonding Analysis of the Tetrylynes HEEH (E = C -- Pb). 
505 8 |a 2.5 Explaining the Different Structures of the Tetrylynes HEEH (E = C -- Pb)2.6 Energy Decomposition Analysis of the Tetrylynes HEEH (E = C -- Pb); 2.7 Conclusion; Acknowledgment; References; Chapter 3 The Role of Recoupled Pair Bonding in Hypervalent Molecules; 3.1 Introduction; 3.2 Multireference Wavefunction Treatment of Bonding; 3.3 Low-Lying States of SF and OF; 3.4 Low-Lying States of SF2 and OF2 (and Beyond); 3.4.1 SF2(X1A1); 3.4.2 SF2(a3B1); 3.4.3 SF2(b3A2); 3.4.4 OF2(X1A1); 3.4.5 Triplet states of OF2; 3.4.6 SF3 and SF4; 3.4.7 SF5 and SF6; 3.5 Comparison to Other Models. 
505 8 |a 3.5.1 Rundle-Pimentel 3c-4e Model3.5.2 Diabatic States Model; 3.5.3 Democracy Principle; 3.6 Concluding Remarks; References; Chapter 4 Donor-Acceptor Complexes of Main-Group Elements; 4.1 Introduction; 4.2 Single-Center Complexes EL2; 4.2.1 Carbones CL2; 4.2.2 Isoelectronic Group 15 and Group 13 Homologues (N+)L2 and (BH)L2; 4.2.3 Donor-Acceptor Bonding in Heavier Tetrylenes ER2 and Tetrylones EL2 (E = Si -- Pb); 4.3 Two-Center Complexes E2L2; 4.3.1 Two-Center Group 14 Complexes Si2L2 -- Pb2L2 (L = NHC); 4.3.2 Two-Center Group 13 and Group 15 Complexes B2L2 and N2L2; 4.4 Summary and Conclusion. 
505 8 |a 5.9 Electronic Structure of Elemental Boron and Boron-Rich Metal Borides -- Application of Electron-Counting Rules. 
520 |a "A unique overview of the different kinds of chemical bonds that can be found in the periodic table, from the main-group elements to transition elements, lanthanides and actinides. It takes into account the many developments that have taken place in the field over the past few decades due to the rapid advances in quantum chemical models and faster computers. This is the perfect complement to "Chemical Bonding - Fundamentals and Models" by the same editors, who are two of the top scientists working on this topic, each with extensive experience and important connections within the community."--  |c Provided by publisher. 
650 0 |a Chemical bonds  |x Mathematical models. 
650 0 |a Chemical bonds  |v Congresses. 
650 4 |a Chemistry  |x Textbooks. 
650 4 |a Chemistry. 
650 4 |a Molecules. 
650 7 |a SCIENCE  |x Chemistry  |x Physical & Theoretical.  |2 bisacsh 
650 7 |a Chemical bonds.  |2 fast  |0 (OCoLC)fst00852856 
655 4 |a Electronic books. 
655 0 |a Electronic books. 
700 1 |a Frenking, G.  |q (Gernot),  |e editor. 
700 1 |a Shaik, Sason S.,  |d 1943-  |e editor. 
776 0 8 |i Print version:  |t Chemical bond : chemical bonding across the periodic table.  |d Weinheim, Germany : Wiley-VCH Verlag GmbH & Co, ©2014  |h xxii, 544 pages  |z 9783527333158 
856 4 0 |u https://doi.org/10.1002/9783527664658  |z Full Text via HEAL-Link 
994 |a 92  |b DG1