Micro- and nanostructured epoxy/rubber blends /

• Άλλοι συγγραφείς: Thomas, Sabu (Επιμελητής έκδοσης), Sinturel, Christophe (Επιμελητής έκδοσης), Thomas, Raju (Επιμελητής έκδοσης)
• Μορφή: Ηλ. βιβλίο
• Γλώσσα: English
• Έκδοση: Weinheim, Germany : Wiley-VCH, 2014.
• Θέματα: Elastomers.; Polymers.; Nanostructured materials.; TECHNOLOGY & ENGINEERING > Chemical & Biochemical.; Electronic books.

From the liquid stage, via phase separation right up to the final network, this book covers every aspect of epoxy toughening. It provides a comprehensive review of the latest research and development in the field, explaining in detail thermal, optical, mechanical and electrical characterization meth...

Πίνακας περιεχομένων:

• Micro- and Nanostructured Epoxy/Rubber Blends; Contents; Preface; List of Contributors; Chapter 1 Introduction; 1.1 Epoxy Resin
• Introduction; 1.2 Cure Reactions; 1.3 Curing Agents; 1.3.1 Catalytic Cure; 1.3.2 Co-reactive Cure; 1.3.2.1 Primary and Secondary Amines; 1.3.2.2 Mercaptans; 1.3.2.3 Isocyanates; 1.3.2.4 Carboxylic Acids; 1.3.2.5 Acid Anhydrides; 1.4 Different Curing Methods; 1.4.1 Thermal Curing; 1.4.2 Microwave Curing; 1.4.3 Radiation Curing; 1.4.3.1 Electron Beam Curing; 1.4.3.2 Gamma Ray Irradiation; 1.5 Curing of Epoxy Resins: Structure-Property Relationship.
• 1.6 Toughening of Epoxy Resin1.6.1 Different Toughening Agents; 1.6.1.1 Liquid Elastomers for Toughening Epoxy Matrices; 1.6.1.2 Rigid Crystalline Polymers; 1.6.1.3 Hygrothermal Toughening Agents; 1.6.1.4 Core-Shell Particles; 1.6.1.5 Nanoparticles for Epoxy Toughening; 1.6.1.6 Thermoplastic Modification of Epoxy Resin; 1.6.1.7 Block Copolymers as Modifiers for Epoxy Resin; 1.7 Rubber-Modified Epoxy Resin: Factors Influencing Toughening; 1.7.1 Concentration Effects; 1.7.2 Particle Size and Distribution of Rubber; 1.7.3 Effect of Temperature; 1.7.4 Effect of Rubber; 1.7.5 Interfacial Adhesion.
• 1.8 Toughening Mechanisms in Elastomer-Modified Epoxy Resins1.8.1 Particle Deformation; 1.8.2 Shear Yielding; 1.8.3 Crazing; 1.8.4 Simultaneous Shear Yielding and Crazing; 1.8.5 Crack Pinning; 1.8.6 Cavitation and Rumples; 1.9 Quantitative Assessment of Toughening Mechanisms; 1.10 Introduction of Chapters; References; Chapter 2 Liquid Rubbers as Toughening Agents; 2.1 Introduction; 2.2 Toughening of Thermoset Resins; 2.3 Fracture Behavior of Rubber-Toughened Thermosets; 2.4 Natural Rubbers; 2.4.1 Preparation Method of LNR; 2.4.1.1 Oxidation in the Presence of Redox System.
• 2.4.1.2 Oxidation by Photochemical Method2.4.1.3 Oxidation at High Temperatures and High Pressures; 2.4.1.4 Oxidation by Cleavage Reagent Specific to Double Bonds; 2.4.1.5 Metathesis Degradation; 2.5 Liquid-Toughening Rubber in Thermoset Resins; 2.6 Concluding Remarks; References; Chapter 3 Nanostructured Epoxy Composites; 3.1 Introduction; 3.2 Preparation Methods of the Nanostructured Epoxy Thermoset; 3.3 Morphology of the Nanostructured Epoxy Thermoset; 3.3.1 Parameters Controlling the Morphologies; 3.3.1.1 Blends Composition; 3.3.1.2 The Choice of Curing Agent.
• 3.3.1.3 Topological Architecture of the Copolymer3.4 Microphase Separation Mechanism; 3.4.1 Self-Assembly Mechanism; 3.4.2 Reaction-Induced Microphase Separation Mechanism; 3.5 Mechanical and Thermal Properties; 3.5.1 Fracture Toughness; 3.5.2 Glass Transition Temperature; 3.6 Conclusions and Outlooks; References; Chapter 4 Manufacture of Epoxy Resin/Liquid Rubber Blends; 4.1 Introduction; 4.2 Comparison of Hardeners; 4.3 Rubber-Toughened Epoxy Resins; 4.4 Cure Reaction Analysis; 4.5 Conclusions; References; Chapter 5 Cure and Cure Kinetics of Epoxy-Rubber Systems; 5.1 Introduction.