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04265nam a2200421 4500 |
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ocn973493151 |
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OCoLC |
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20180501122035.0 |
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m o d |
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cr cnu---unuuu |
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170223s2017 mau o 001 0 eng d |
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|a OPELS
|b eng
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|c OPELS
|d EBLCP
|d OCLCF
|d GrThAP
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|a 9780128111055
|q (print)
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|a (OCoLC)973493151
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|a QD474
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|a 541/.2242
|2 23
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|a TEFA
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|a Polyoxometalate chemistry /
|c edited by Rudi van Eldik and Leroy Cronin.
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|a Cambridge, MA :
|b Academic Press,
|c 2017.
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|a 1 online resource.
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|a text
|b txt
|2 rdacontent
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|a computer
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|2 rdamedia
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|a online resource
|b cr
|2 rdacarrier
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|a Advances in inorganic chemistry ;
|v volume 69
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|a Includes index.
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|a Online resource; title from PDF title page (ScienceDirect, viewed February 23, 2017).
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|a Front Cover; Polyoxometalate Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: Exploring Self-Assembly and the Self-Organization of Nanoscale Inorganic Polyoxometalate Clusters; 1. Introduction to Polyoxometalate Chemistry; 1.1. Background; 1.2. Classification of the Polyoxometalate Family; 2. From Serendipity to Directed Assembly; 3. Synthetic Methodologies; 3.1. Ligands and Metal Cations as Assembly Directing Motifs; 3.2. Templated Assembly; 3.3. Reductively Triggered Assembly; 4. POM-Based Supramolecular Structures; 4.1. POM Nanostructures
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|a 5. From Self-Assembled to Self-Organizing Cluster Systems6. Conclusions; References; Chapter Two: Supramolecular Structures Formation of Polyoxometalates in Solution Driven by Counterion-Macroion Interaction; 1. Introduction; 2. Self-Assembly of POM Macroions Into ``Blackberries;́́ 3. Counterion-Mediated Self-Assembly of POM Macroions; 3.1. Driving Force for Blackberry Formation; 3.2. Counterion Distribution in POM Solutions; 3.3. Counterion Exchange Around POMs; 3.4. Self-Assembly With Anisotropic Surface Charge Density Distribution; 4. The Kinetic Properties and Lag Phase of POM Assembly
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|a 5. POM-Counterion Ion Pairing in Solution6. Dynamic of Alkali Counterions in POM Solution; 7. Cation Transportation Through Blackberry ``Membrane;́́ 8. Selective Permeability of Uranyl Peroxide Nanocage; 8.1. Role of Hydration Layer in Selective Permeability of U60; 8.2. Controlling the Ion Selectivity of U60; 9. Self-Recognition Behaviors During Their Self-Assembly; 10. Simulation Studies on Self-Assembly of POM Macroions; 11. Conclusions; Acknowledgments; Reference; Chapter Three: Electron Transfer-Oxygen Transfer Reactions and Beyond With Polyoxometalates
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|a 1. Mechanisms for the Aerobic Oxidation of Organic Compounds2. The H5PV2Mo10O40 Polyoxometalate and Electron Transfer Oxidations; 3. The First Example of Electron Transfer-Oxygen Transfer Catalyzed by H5PV2Mo10O40; 4. Oxidation of Sulfides; 5. Oxidation of Primary and Vicinal Alcohols; 6. Oxidation of via Activation of C-H Bonds Revisited; 7. Insertion of Oxygen Into a Carbon-Metal Bond; 8. The Structure of H5PV2Mo10O40 During the Catalytic Reaction; 9. Conclusions; Acknowledgments; References; Chapter Four: Oxygen-Isotope Exchange and Metastable Dissociation in Oxides; 1. Introduction
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|a 2. Broad Reactivity Trends for Dissolving Materials and Glasses3. Acid-Base Chemistry and Reactivity in Niobates; 4. The Transition to a Partly Detached Structure in MAl12 Cations; 5. Metastable Intermediates; 6. Conclusions; Acknowledgments; References; Chapter Five: Polyoxometalate Multielectron Catalysts in Solar Fuel Production; 1. Introduction; 2. Definitions; 2.1. Reaction Thermodynamics of Water Splitting; 2.2. Photochemical Generation of Oxidant/Reductant; 3. Water Splitting Overview; 3.1. Experimental Approaches to Evaluate WOCs and Water Reduction Catalysts
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|a Polyoxometalates.
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|a Polyoxometalates.
|2 fast
|0 (OCoLC)fst01070737
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|a Electronic books.
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|a Eldik, Rudi van,
|e editor.
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| 700 |
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|a Cronin, Lee,
|e editor.
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|a Advances in inorganic chemistry ;
|v v. 69.
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4 |
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|u https://www.sciencedirect.com/science/bookseries/08988838/69
|z Full Text via HEAL-Link
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