Inorganic Reaction Mechanisms /

• Other Authors: Eldik, Rudi van (Editor), Hubbard, Colin D. (Editor)
• Format: eBook
• Language: English
• Published: London : Academic Press, an imprint of Elsevier, 2017.
• Edition: First edition.
• Series: Advances in inorganic chemistry ; v. 70.
• Subjects: Chemistry, Inorganic.; SCIENCE / Life Sciences / Biochemistry; Electronic books.

Inorganic Reaction Mechanisms, Volume 70, is the latest volume from the Advances in Inorganic Chemistry series, which presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bio-inorganic to solid state studies. This ac...

Table of Contents:

• Title page; Table of Contents; Copyright; Dedication; Ralph G. Wilkins; Contributors; Preface; Chapter One: The Kinetics and Mechanism of Complex Redox Reactions in Aqueous Solution: The Tools of the Trade; Abstract; 1 Introduction; 2 General Considerations; 3 Selected Reactions of Oxychlorine Species; 4 Kinetics of the Oxidation Reactions of Peroxo Compounds; 5 The Photon as a Reactant; 6 Selected Kinetic Studies on Heterogeneous Systems; 7 Concluding remarks; Acknowledgments; Chapter Two: O-O Bond Activation in Cu- and Fe-Based Coordination Complexes: Breaking It Makes the Difference
• Chapter Four: The Role of Nonheme Transition Metal-Oxo, -Peroxo, and -Superoxo Intermediates in Enzyme Catalysis and Reactions of Bioinspired ComplexesAbstract; 1 Introduction; 2 Metal-(Di)oxygen Intermediates; 3 Conclusions; Acknowledgments; Chapter Five: Diarylplatinum(II) Scaffolds for Kinetic and Mechanistic Studies on the Formation of Platinacycles via an Oxidative Addition/Reductive Elimination/Oxidative Addition Sequence; Abstract; 1 Introduction; 2 Compounds; 3 Kinetic Studies; 4 Synergy With DFT Calculations; 5 Concluding Remarks; Acknowledgments
• 3 Thionitrous Acid HSNO and Thionitrite SNO, Elusive Aqueous Intermediates4 Polysulfides and Sulfur Sols; 5 Perthionitrite, S2NO. Identification of Iyellow; 6 Coordination Chemistry of Nitrosothiols, Thionitrous Acid, Thionitrite, and Perthionitrite; 7 Conclusions; Acknowledgments; Chapter Eight: Computational Insights Into the Reactivity at the Sulfur Atoms of M3S4 (M=Mo, W) Clusters: The Mechanism of [3+2] Cycloaddition With Alkynes; Abstract; 1 Introduction: The Reactivity of M3S4 (M=Mo, W) Clusters; 2 Experimental and Computational Methods