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on1076274643 |
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20200326101157.0 |
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m o d |
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181126s2018 enk o 000 0 eng d |
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|a 1066247625
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|2 bisacsh
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|a 547/.13
|2 23
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|a Advances in physical organic chemistry.
|n Volume 52 /
|c edited by Ian H. Williams, Nicholas H. Williams.
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| 264 |
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1 |
|a London, United Kingdom :
|b Academic Press,
|c 2018.
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| 300 |
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|a 1 online resource
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| 336 |
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|a text
|b txt
|2 rdacontent
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| 337 |
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|a computer
|b c
|2 rdamedia
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| 338 |
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|a online resource
|b cr
|2 rdacarrier
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|a Advances in Physical Organic Chemistry Ser. ;
|v v. Volume 52
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|a Online resource; title from PDF title page (ScienceDirect, viewed November 26, 2018).
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|a Front Cover; Advances in Physical Organic Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: The Conundrum of the (C4H7)+ Cation: Bicyclobutonium and Related Carbocations; 1. Introduction; 1.1. Early Studies; 1.2. Terminology; 1.3. Kinetic Isotope Effects; 1.4. Gas-Phase Studies; 1.5. Vibrational Spectroscopy; 1.6. Structures and Equilibrium of Bicyclobutonium and Cyclopropylmethyl Cations; 1.7. NMR Spectroscopic Investigations; 1.8. EIEs on NMR Spectra of Fast-Rearranging (C4H7)+ Cations; 1.9. Quantum-Chemical Calculations of EIEs in (C4H7)+ Cations.
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|a 1.9.1. The Size and the Direction of the EIEs1.9.2. Population of the Equilibrating Sites; 1.9.3. The Size of the EIE; 1.9.4. The EIE-Induced Direction of the NMR Chemical Shifts of the Averaged Methylene Signals; 1.9.5. Quantum-Chemical Calculations for the (C4H7)+ Cation System; 2. Substituted (C4H7)+ Carbocations; 2.1. Fast-Equilibrating Substituted Bicyclobutonium Ions; 2.1.1. Solvolysis Results of Substituted Cyclobutyl Derivatives; 2.2. NMR Spectroscopic and Computational Investigations of Substituted (C4H7)+ Cations; 2.2.1. 1-Methyl-Bicyclobutonium Cation.
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|a 2.2.2. The 1-(Trimethylsilyl)Bicyclobutonium Ion2.3. EIEs in Substituted Cyclopropylmethyl and Substituted Cyclobutyl Cations; 2.4. Static Substituted Bicyclobutonium Ions; 2.5. Spin-Spin Coupling Constants; 2.6. 1,3-Disubstituted Static Bicyclobutonium Ions; 3. Conclusion; References; Chapter Two: Organic Reaction Outcomes in Ionic Liquids; 1. Introduction; 1.1. Scope of This Review; 1.2. Ionic Liquids: Common Structures and Nomenclature; 2. Understanding Reaction Outcomes in Ionic Liquids: Key Milestones; 2.1. Not All Ionic Liquids Are Created Equal.
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|a 2.2. The Importance of the Proportion of the Ionic Liquid in the Reaction Mixture2.3. Understanding the Microscopic Origins of Ionic Liquid Effects; 2.4. Correlating Reaction Outcomes With Solvent Parameters; 3. Opportunities Delivered by the Understanding Gained; 3.1. Extending the Knowledge to Other Systems; 3.2. Rational Design of an Ionic Liquid Solvent; 3.3. Biasing Product Selectivity; 4. Summary and Outlook; Acknowledgments; References; Chapter Three: Polymer Mechanochemistry: A New Frontier for Physical Organic Chemistry; 1. Introduction.
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|a 2. A Quantitative Model of Mechanochemical Kinetics2.1. Approximate Solutions of the Master Equation of Mechanochemical Kinetics; 2.1.1. Zeroth-Order Approximation: The EB Model; 2.1.2. First-Order Approximation: Tilted Potential Energy Surface (TPES) and Cusp Models; 2.1.3. Second-Order and Complete Harmonic Approximations; 2.2. Accuracy of the Conventional Approximations and Systematic Strategies of Improving Them; 2.3. Complicating Factors: Ensemble Effects, the Minimum Length of the Macromolecular Segment, Multibarrier Reactions, an ...
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| 650 |
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|a Physical organic chemistry.
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| 650 |
|
7 |
|a SCIENCE
|x Chemistry
|x Organic.
|2 bisacsh
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| 650 |
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7 |
|a Physical organic chemistry.
|2 fast
|0 (OCoLC)fst01715687
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| 650 |
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|a Fisico-Quimica (Organica)
|2 larpcal
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| 655 |
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|a Electronic books.
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| 700 |
1 |
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|a Williams, Ian,
|e editor.
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| 700 |
1 |
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|a Williams, Nick,
|e editor.
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| 776 |
0 |
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|i Print version:
|a Gold, V.
|t Advances in physical organic chemistry.
|d London : Academic Press, 1969-
|z 9780128152119
|w (OCoLC)37236247
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| 830 |
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0 |
|a Advances in Physical Organic Chemistry Ser.
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| 856 |
4 |
0 |
|3 ScienceDirect
|u https://www.sciencedirect.com/science/bookseries/00653160/52
|z Full Text via HEAL-Link
|
