Late Transition Metal-Carboryne Complexes Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes /

• Main Author: Qiu, Zaozao (Author)
• Corporate Author: SpringerLink (Online service)
• Format: Electronic eBook
• Language: English
• Published: Berlin, Heidelberg : Springer Berlin Heidelberg, 2012.
• Series: Springer Theses
• Subjects: Chemistry.; Inorganic chemistry.; Organic chemistry.; Medicinal chemistry.; Organic Chemistry.; Inorganic Chemistry.; Medicinal Chemistry.

In this thesis, Zaozao Qiu shows that transition metals can mediate or catalyze cycloaddition and coupling reactions of carboryne with alkynes or alkenes. These reactions afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes, and are powerful strategies to assemble useful complex molec...

Table of Contents:

• Introduction
• Nickel-1,2-o-Carboryne Complexes
• Nickel-Mediated Coupling Reactions of 1,2-o-Carboryne with Alkenes
• Nickel-Mediated/Catalyzed Three-Component Cycloaddition Reaction of 1,2-o-Carboryne/Arynes, Alkenes, and Alkynes
• Nickel-Catalyzed Regioselective [2+2+2] Cycloaddition of 1,2-o-Carboryne with Alkynes
• Palladium/Nickel-Cocatalyzed [2+2+2] Cycloaddition of 1,3-o-Carboryne with Alkynes
• Conclusion
• Experimental Section.