The Chemistry of Zirconacycles and 2,6-Diazasemibullvalenes Synthesis, Structures, Reactions, and Applications in the Synthesis of Novel N-Heterocycles /

• Main Author: Zhang, Shaoguang (Author)
• Corporate Author: SpringerLink (Online service)
• Format: Electronic eBook
• Language: English
• Published: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 2015.
• Series: Springer Theses, Recognizing Outstanding Ph.D. Research,
• Subjects: Chemistry.; Organometallic chemistry.; Physical chemistry.; Chemistry, Physical and theoretical.; Crystallography.; Organometallic Chemistry.; Physical Chemistry.; Theoretical and Computational Chemistry.

In this thesis, the author introduces two strategies used to construct various types of N-heterocycles, based on the chemistry of zirconacycles and 2,6-diazasemibullvalenes. In the first part, the author presents the development of multi-component cyclization of a zirconacyclobutene-silacyclobutene...

Table of Contents:

• Introduction to Zirconacycle Chemistry
• Zirconocene-Mediated Cyclization of Bis(alkynyl)silanes and Nitriles: Synthesis of N-Heterocycles and Isolation, Characterization and Synthetic Application of Zr/Si-containing Reactive Intermediates
• Bulky-Nitrile Coordination Induced Skeleton Rearrangement of Zr/Si-containing Metallacycles and Selective Synthesis of 5-Azaindoles
• Introduction to Semibullvalenes and Azasemibullvalenes
• 2,6-Diazasemibullvalenes: Synthesis, Structure, Theoretical Analysis and Computational Chemistry
• 2,6-Diazasemibullvalenes: Reaction Chemistry and Synthetic Application.